Trustor Coatings, 401 North 72 nd Ave., Wausau, WI 54401
24 Hour Emergency Telephone: (715) 849-8080
Section 1. PRODUCT IDENTIFICATION
PRODUCT NAME: 6400 CATALYST FOR HYDROIL PRIMER (WATER BORNE )
CHEMICAL FAMILY: MIXTURE OF ALIPHATICE ISOCYANATES
Section 2. HAZARDOUS INGREDIENTS AND EXPOSURE LIMITS
Substances presenting a health hazard within the meaning of the Dangerous Substances Directive 67/548/EEC
CAS
Chemical Name Number Conc. Phrases
Hexane, 1,6 Diisocyantat 28182-81-2 50 – 100%
Hexamethylene Diisocyanate 822-06-0 > 0.15%
1-methoxy-
2-acetoxypropane 000108-35-6 10 – 25 % none
1.669 lbs./Gal.
(See full text of R phrases under chapter 16)
Section 3. HAZARDS IDENTIFICATION
A. Emergency Overview:
Physical Appearance: Colorless to pale yellow viscous liquid.
Warning Statements: Caution! Eye irritant. Toxic if inhaled. Possible sensitizer. Reacts with common materials including Water, Alcohols, Bases and Amines Releasing Large amounts of Carbon Dioxide, May cause skin, eye and Respiratory Tract irritation. May cause allergic skin reaction.
B. Potential Health Effects:
Acute Eye:
May cause irritation
Acute Skin:
May cause allergic reaction, May cause irritation.
Acute Inhalation:
May be harmful if inhaled. May cause shortness of breath, headache, nausea, vomiting, respiratory tract irritation.
Acute Ingestion:
May be harmful if swallowed.
Chronic Effects:
This Product does not contain any ingredient designated by IARC, NTP, ACGIH or OSHA as probable or suspected human carcinogens.
Section 4. FIRST AID MEASURES
First Aid and measures for accidental:
Eye Exposure:
Hold Eye open and flush with steady, gentle stream of water for at least minutes> Seek medical attention.
Skin Exposure:
In case of contact, immediately wash with plenty of soap and Water for at least 5 minutes. Seek medical attention. Remove contaminated clothing and shoes. Clean contaminated clothing and shoes before re-use.
Inhalation:
If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if respiratory irritation or distress continues.
Ingestion:
If victim is conscious and alert, give 2 – 3 glasses of water and induce vomiting by touching back of throat with finger. Do not induce vomiting or give anything by mouth to an unconscious person. Seek immediate medical attention. Do not leave victim unattended. Vomiting may occur spontaneously. To prevent aspiration of swallowed product, lay victim on side with head lower than waist. If vomiting occurs and victim is conscious, give water to further dilute the chemical.
Medical Conditions possibly aggravated by exposure:
Skin contact may aggravate existing skin disease.
Notes to Physician:
All Treatments should be based on observed signs and symptoms of distress of the patient. Consideration should be given to the possibility that overexposure to materials other than this might have occurred.
Treat symptomatically. No specific antidote available.
Section 5. FIRE – FIGHTING MEASURES
Flammable Properties
Flash Point: 114°F, 46°C Method used: Setaflash closed cup, ASTM D3278
Auto Ignition Temperature: 333°C
Flammability Limits:
LFL: 1.5 vol.% @ 200°C
UFL: 7.0 vol. % @ 200°C
Other Flammability Information:
Violent steam generation or eruption may occur upon application of direct water stream to hot liquids. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and /or flash back may occur. Spills of these organic liquids on hat fibrous insulations may lead to the lowering of the auto ignition temperatures possibly resulting in spontaneous combustion.
Extinguishing media:
Recommended: alcohol resistant foam (ATC type are preferred), CO2, powders. Not recommended water.
Fire Fighting Instructions:
Keep people away. Isolate fire and deny unnecessary entry. Burning liquid might be moved by flushing with water. Cool closed containers and fire exposed zone with water until fire is extinguished and danger of re ignition has passed. Eliminate ignition sources. Stay up wind. Do not allow run off from fire fighting to enter drains or watercourses.
Hazardous Combustions Products:
Due to the organic solvents content of the preparation, fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Smoke may contain the original Material in addition to other toxic and /or irritating compounds. Hazardous products may include and are not limited to: Carbon monoxide, Carbon dioxide, oxides of Nitrogen other toxic and corrosive fumes might be emitted.
Protective Equipment for Fire fighting:
Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing, including Helmet, Coat, Pants, Boots, and Gloves. If protective equipment is not available or not used, fight fire from a protected location or safe distance.
Section 6. ACCIDENTAL RELEASE MEASURES
Evacuation Procedures and safety:
Wear appropriate protective gear for the situation. See personal Protection information in Section 8.
Eliminate all sources of ignition in vicinity of spills or released vapor to avoid explosion.
Containment of Spill:
Follow procedure described under Clean up and Disposal of Spill.
Dike spill using absorbent or impervious materials such as earth, sand or clay. Collect and contain contaminated absorbent and dike material for disposal.
Clean Up and Disposal of Spill:
Pump any free liquid into an appropriate closed container (See Section 7). Clean up spill area with a decontamining solution made up with 50% isopropyl alcohol, 45% Water and 5% concentrated Ammonia (%by weight). The solution should cover the area for at least 1 hour. Absorb with inert absorbent. Collect all materials and washings for disposal.
Environmental and regulatory Reporting:
Do not flush into drain. Spills may be reportable to National Response Center (800 424 8802) and /or to local agencies.
Section 7. HANDLING AND STORAGE
Minimum/Maximum Storage Temperatures:
Not available
HANDLING:
Do not get in Eyes. Avoid direct or prolonged contact with skin. Store, transfer and handle under blanket of nitrogen. Before closing partially empty containers., blanket with dry nitrogen. Replace damaged gaskets. Containers, even those that have been emptied can contain vapors. Do not cut, weld or perform similar operations on or near empty containers. No smoking, open flames or sources of Ignition in handling and storage area. Never use air pressure for transferring product. Electrically ground all equipment.
STORAGE:
Store in tightly closed original containers. Do not store in copper, polystyrene or tin containers. Store in a dry , well ventilated area only.
Section 8. EXPOSURE CONTROL/PERSONAL PROTECTION
Exposure Guidelines:
Exposure limits represent regulated or recommended worker breathing zone concentrations measured by validated and analytical methods, meeting the regulatory requirements. The following limits apply to this material, where if indicated, S=Skin and C=ceiling limit.
Hexamethylene Diisocyante (HDI)
Notes TWA STEL
ACGIH 0.005 ppm
Engineering Controls:
Where engineering controls are indicated by use conditions or a potential for excessive exposure exists, the following traditional exposure control techniques may be used to effectively minimize employee exposures: General Area dilution/exhaust ventilation.
Respiratory Protection:
When respirator are required select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations. Under normal conditions, in the absence of other airborne contaminants, the following devices should provide protection from this material up to the conditions specified by the appropriate OSHA, WHMIS or ANSI standards: Full Face air purifying respirators are required in work environments where airborne concentrations exceed the action level but are significantly lower than the IDLH provided that cartridges are changed daily. Use combination HEPA filter for the polyisocyanate aerosol and an organic vapor cartridge for the solvents used. Install organic vapor cartridge closest to face.
Eye/Face Protection:
Eye and Face protection requirements will vary dependent upon work environment conditions and material handling practices. Appropriate ANSI Z87 approved equipment should be selected for the particular use of this material.
Eye Protection:
Eye contact should be prevented through use of chemical safety glasses with side shields or splash proof goggles. An emergency wash must be readily accessible to the work area.
Skin Protection:
Skin Protection should be minimized through use of gloves and suitable long sleeved clothing (i.e. shirts and pants). Consideration must be given to both, durability as well as permeation resistance.
Work practice Controls:
Personal hygiene is an important work practice exposure control measure and the following general measures should be taken when working with or handling this product:
Do not store , use and/or consume foods, beverages, tobacco products, or cosmetics in areas where this material is stored.
Wash hands and face carefully before eating, drinking using tobacco, applying cosmetics, or using the toilet.
Wash exposed skin promptly to remove accidental splashes or contact with this material.
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Appearance colorless to pale yellow viscous liquid
Odor specific sweet ether odor
pH not applicable
Specific Gravity 1.12 kg/ltr. or 9.36 lbs./Gal.
Water solubility reacts
Boiling Point 295°F or 145°C
Vapor pressure 3.7 mmHg@20°C
Vapor density 4.6
VOC content 193.2 gr./ltr.
Section 10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: This material is stable under normal handling and storage conditions described in Section 7
Conditions to be avoided:
Extreme heat, Open Flame
Material/Chemicals to be avoided:
Strong bases, strong acids, strong oxidizing agents, amines.
Following hazardous decomposition products might be expected:
Decomposition type: Thermal
Oxides of nitrogen
Oxides of Carbon
Section 11. TOXICOLOGICAL INFORMATION
Toxicological Information and Interpretation:
Acute Eye Irritation:
Eye irritation: 0.1 ml. Rabbit.
mildly irritating.
Acute Skin irritation:
Skin irritation : 0.5 ml. Rabbit
Slightly irritating.
Skin sensitization, guinea pig.
Sensitizing.
Acute Dermal Toxicity:
LD 50 – lethal dose of test species > 2000 mg/kg, rabbit.
Acute Respiratory Irritation:
Slightly to moderately irritating.
Acute Inhalation Toxicity:
LC 50 – lethal concentration 50% of test species, 2.18 mg/1/4 hr. rat.
Acute Oral Toxicity:
LD 50 – lethal dose of 50% of test species > 5000mg/kg. Rat
Chronic Toxicity:
This product does not contain any substances that are considered by OSHA, NTP, IARC or ACGIH to be “probable” or “suspected” human carcinogens.
No additional test data available for this product.
Section 12. ECOLOGICAL INFORMATION
There are no data available on the preparation itself. The product should not be allowed to enter drains or watercourses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under Environment Protection Act may apply to the use of this product.
Section 13. DISPOSAL CONSIDERATIONS
Please be advised that state and local requirements for waste disposal may be more restrictive or otherwise different from regulations from federal laws and regulations. Consult state and local regulations regarding proper disposal of this material.
Container Handling and Disposal:
Any containers or equipment used should be decontaminated immediately after use. Decontaminate containers with the solution given under Section 6
Containers should be crushed or punctured.
EPA Hazardous Waste – NO
Section 14. TRANSPORT INFORMATION
Transportation Status: IMPORTANT! Statements below provide additional data on listed DOT classification.
The listed Transportation Classification does not address regulatory variations due changes in package size, mode of shipment or other regulatory descriptors.
Shipping Name:
Not regulated
Section 15. REGULATORY INFORMATION
Inventory Status:
Inventory Status
USA (TSCA) Y
Canada (DSL) Y
Europe (EINECS/ELINCS P
Australia Y
Japan (MITI) Y
Y = All Ingredients are on the inventory
P = One or more ingredients fall under the polymer exemption or are on the no longer polymer list. All other ingredients are not on the inventory or exempt from listing.
All functional components of this product are listed on the TSCA inventory.
SARA Title III Hazard Classes:
Fire Hazard Yes
Reactive Hazard Yes
Release of Pressure No
Acute Health Hazard Yes
Chronic Health Hazard No
Section 16. OTHER INFORMATION
HMIS Hazard ratings:
Health 2 moderate
Flammability: 2 moderate
Reactivity 1 slight
Personal Protection: see section 8
NFPA Hazard Ratings
Health 2 moderate
Flammability 2 moderate
Instability 1 slight
The information of this MSDS is based on the present state of our knowledge and on current EEC and national laws as the user’s working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified under section 1 without first obtaining written handling instructions. It is always the responsibility of the user to take all necessary steps in order to fulfill the demand laid down in the local rules and legislation. The information in this MSDS is meant as a description of the safety requirements of our product; it is not to be considered as a guarantee of the properties of the product.
Trustor Coatings believes the statements, technical information and recommendations contained herein are reliable. They are given without warranty or guarantee of any kind, expressed or implied.
DATE ISSUED: June 9, 2004 PREPARED BY: Trustor Coatings
